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"Sex on Fire" is the first single to be taken from Kings of Leon's fourth studio album Only by the Night and as of September 2009, the second most-downloaded digital single ever in the United Kingdom.
The song gave Kings of Leon their first number-one single in Australia, Finland, Ireland and United Kingdom, charting at the top-spot in the UK Singles Chart on digital downloads alone, before its physical release. It has also gained significant popularity in the United States .